Kodomo no Jikan
Alternative title: A Childs Time, Kojika
Story Overview
Daisuke is a 23 year-old new schoolteacher. He ends up being put in charge of a 3rd grade elementary school class since the previous teacher quit, and in that class there is a girl who is quite a troublemaker--Rin Kokonoe. You could call her a masegaki (used to describe a kid that acts more like an adult in some ways), and she is also part tsundere (though more dere than tsun).